Chemical Bond of the Month July 2017 |
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Dynamic Breaking of a Single Gold-Gold Bond | ||
Theoretically, a stretched chemical bond exhibits a dynamic breaking behavior due to the competition between the spontaneous thermally-activated and mechanically-activated breaking mechanisms: the breaking force is constant at low force loading rates (FLRs), increases at intermediate FLRs and reaches a constant value at high FLRs. For the first time, the dynamic breaking behavior was demonstrated for a single chemical bond between two gold atoms in current-sensing atomic force microscopy experiments (Dr. Ilya Pobelov and the group of Prof. Wandlowski) and explored in molecular dynamics simulations (Prof. Gemma Solomon, University of Copenhagen). References:
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